[Pt2(PPh3)4(μ-S)2] as a metalloligand towards main-group Lewis acids. Evidence of a sulfide-linked {BiPt4} aggregate by 1/2 addition on BiCl3

Please use this identifier to cite or link to this item: https://doi.org/10.1016/0277-5387(95)00519-6

Title:	[Pt2(PPh3)4(μ-S)2] as a metalloligand towards main-group Lewis acids. Evidence of a sulfide-linked {BiPt4} aggregate by 1/2 addition on BiCl3
Authors:	Zhou, M. Leung, P.-H. Mok, K.F. Hor, T.S.A.
Issue Date:	May-1996
Citation:	Zhou, M., Leung, P.-H., Mok, K.F., Hor, T.S.A. (1996-05). [Pt2(PPh3)4(μ-S)2] as a metalloligand towards main-group Lewis acids. Evidence of a sulfide-linked {BiPt4} aggregate by 1/2 addition on BiCl3. Polyhedron 15 (10) : 1737-1741. ScholarBank@NUS Repository. https://doi.org/10.1016/0277-5387(95)00519-6
Abstract:	Chloride dissociation of [(PPh3)4Pt2(μ3-S) 2BiCl3] (2) followed by addition of [Pt2(PPh3)4(μ-S)2] (1) gave a bis-bidentate complex [{(PPh3)4Pt2(μ3-S) 2}2BiCl2]Cl (4), which regenerated 2 in CH2Cl2. Complex 4 represents the first example of a main-group complex incorporating two bulky thio ligands of 1.
Source Title:	Polyhedron
URI:	http://scholarbank.nus.edu.sg/handle/10635/92888
ISSN:	02775387
DOI:	10.1016/0277-5387(95)00519-6
Appears in Collections:	Staff Publications

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