Please use this identifier to cite or link to this item:
|Title:||"click-and-click"-hybridised 1,2,3-triazoles supported Cu(i) coordination polymers for azide-alkyne cycloaddition|
|Source:||Jiang, L., Wang, Z., Bai, S.-Q., Hor, T.S.A. (2013-07-14). "click-and-click"-hybridised 1,2,3-triazoles supported Cu(i) coordination polymers for azide-alkyne cycloaddition. Dalton Transactions 42 (26) : 9437-9443. ScholarBank@NUS Repository. https://doi.org/10.1039/c3dt50987g|
|Abstract:||Two novel pyridyl and thioether hybridised 1,2,3-triazole ligands 1-(2-picolyl)-4-(2-(methylthio)-pyridine)-1H-1,2,3-triazole (L1) and 1-(4-picolyl)-4-(2-(methylthio)-pyridine)-1H-1,2,3-triazole (L2) were prepared from CuAAC click reactions. Reactions of CuI with the ligands L1 and L2 yielded two one-dimensional coordination polymers [Cu6I6(L1) 2]n (1) and [Cu2I2(L2) 2]n (2). Single-crystal X-ray diffraction reveals that 1 and 2 are polymeric with [Cu6I6] and [Cu2I 2] respectively as building blocks. Both ligands (L1 and L2) and complexes (1 and 2) are photoluminescence active. Complexes 1 and 2 are also catalytically active towards azide-alkyne cycloaddition reactions. This journal is © The Royal Society of Chemistry 2013.|
|Source Title:||Dalton Transactions|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Feb 15, 2018
WEB OF SCIENCETM
checked on Jan 30, 2018
checked on Feb 19, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.