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|Title:||"click-and-click"-hybridised 1,2,3-triazoles supported Cu(i) coordination polymers for azide-alkyne cycloaddition|
|Citation:||Jiang, L., Wang, Z., Bai, S.-Q., Hor, T.S.A. (2013-07-14). "click-and-click"-hybridised 1,2,3-triazoles supported Cu(i) coordination polymers for azide-alkyne cycloaddition. Dalton Transactions 42 (26) : 9437-9443. ScholarBank@NUS Repository. https://doi.org/10.1039/c3dt50987g|
|Abstract:||Two novel pyridyl and thioether hybridised 1,2,3-triazole ligands 1-(2-picolyl)-4-(2-(methylthio)-pyridine)-1H-1,2,3-triazole (L1) and 1-(4-picolyl)-4-(2-(methylthio)-pyridine)-1H-1,2,3-triazole (L2) were prepared from CuAAC click reactions. Reactions of CuI with the ligands L1 and L2 yielded two one-dimensional coordination polymers [Cu6I6(L1) 2]n (1) and [Cu2I2(L2) 2]n (2). Single-crystal X-ray diffraction reveals that 1 and 2 are polymeric with [Cu6I6] and [Cu2I 2] respectively as building blocks. Both ligands (L1 and L2) and complexes (1 and 2) are photoluminescence active. Complexes 1 and 2 are also catalytically active towards azide-alkyne cycloaddition reactions. This journal is © The Royal Society of Chemistry 2013.|
|Source Title:||Dalton Transactions|
|Appears in Collections:||Staff Publications|
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