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|Title:||Synthesis, photophysics, and electroluminescence of poly(dibenzofluorene)s|
|Citation:||Wang, W.-Z., Zhu, R., Fan, Q.-L., Xu, H., Hou, L.-T., Cao, Y., Huang, W. (2006-07-24). Synthesis, photophysics, and electroluminescence of poly(dibenzofluorene)s. Macromolecular Rapid Communications 27 (14) : 1142-1148. ScholarBank@NUS Repository. https://doi.org/10.1002/marc.200600165|
|Abstract:||A series of soluble poly(dibenzofluorene) derivatives that contain dibenzo[a,g]fluorene, dibenzo[a,i]fluorene, and dibenzo[c,g]fluorene repeat units in the main chain have been synthesized, characterized, and explored as emissive materials in polymer light emitting diodes (PLEDs). These polymers possess higher glass transition temperatures (108-133 °C) than that of poly(2,7-(9,9-dialkyl)fluorene) (PFO). The photophysical and electrochemical properties of these polymers are affected by the steric hindrance effect. These polymers emit blue light in dilute solution (378-400 nm) and in the solid state (426-447 nm). As emissive materials in PLEDs, blue electroluminescence with a brightness of up to 3130 cd m-2 is obtained from single-layer diodes of P2 with aluminum/barium in air. © 2006 WILEY-VCH Verlag GmbH & Co. KGaA.|
|Source Title:||Macromolecular Rapid Communications|
|Appears in Collections:||Staff Publications|
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