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| Title: | Synthesis and characterization of novel reactive polyorganosiloxane containing nitro groups | Authors: | Liu, C.-Q. Liu, Y. Xie, P. Zhang, R.-B. He, C.-B. Chung, N.T.-S. |
Keywords: | Characterization Equilibration polymerization Hydrosilylation Polyorganosiloxane |
Issue Date: | 2001 | Citation: | Liu, C.-Q.,Liu, Y.,Xie, P.,Zhang, R.-B.,He, C.-B.,Chung, N.T.-S. (2001). Synthesis and characterization of novel reactive polyorganosiloxane containing nitro groups. Chinese Journal of Polymer Science (English Edition) 19 (1) : 1-6. ScholarBank@NUS Repository. | Abstract: | A novel reactive polyorganosiloxane containing nitro groups was first prepared by acid-catalyzed equilibration polymerization. The monomer, 3-(4-nitrophenoxy)propylmethyldichlorosilane (NPPMS), was synthesized by hydrosilylation reaction with dicyclopentadienylplatinum(II) chloride (Cp2PtCl2) catalyst in high yield. The synthesized polynitroorganosiloxane, which has potential application as a precursor for synthesizing advanced functional polymers, was characterized by FTIR, 1H-NMR, 13C-NMR, 29Si-NMR, vapor pressure osmometry (VPO) and gel permeation chromatography (GPC). | Source Title: | Chinese Journal of Polymer Science (English Edition) | URI: | http://scholarbank.nus.edu.sg/handle/10635/92388 | ISSN: | 02567679 |
| Appears in Collections: | Staff Publications |
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