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|Title:||Synthesis and superior third-order nonlinear optical properties of the cluster (n-Bu4N)4[Mo8CU12O8S 24]|
|Authors:||Shi, S. |
|Citation:||Shi, S.,Ji, W.,Xin, X.Q. (1995). Synthesis and superior third-order nonlinear optical properties of the cluster (n-Bu4N)4[Mo8CU12O8S 24]. Journal of Physical Chemistry 99 (3) : 894-898. ScholarBank@NUS Repository.|
|Abstract:||A new inorganic cluster (n-Bu4N)4[Mo8Cu12O8S 24] was synthesized. It proves to be a superior molecular third-order nonlinear optical chromophore. Results from solution measurements of degenerate four-wave mixing and Z-scans at 532 nm show that the observed value of the third-order nonlinear molecular susceptibility, γ, is 5.7 × 10-28 esu with imaginary and real components, Im γ and Re γ, of 0.45 × 10-28 esu and -5.7 × 10-28 esu, respectively. The negative sign of Re γ reveals that the cluster has an interesting optical self-defocusing property. The third-order susceptibility (|χs (3)| = 3 × 10-6 esu, 532 nm) of the molecule in the solid state is extrapolated. © 1995 American Chemical Society.|
|Source Title:||Journal of Physical Chemistry|
|Appears in Collections:||Staff Publications|
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