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|Title:||Modified polyaniline through simultaneous electrochemical polymerization of aniline and metanilic acid|
|Authors:||Lee, J.Y. |
|Source:||Lee, J.Y.,Cui, C.Q.,Su, X.H.,Zhou, M.S. (1993-11-30). Modified polyaniline through simultaneous electrochemical polymerization of aniline and metanilic acid. Journal of Electroanalytical Chemistry 360 (1-2) : 177-187. ScholarBank@NUS Repository.|
|Abstract:||Simultaneous electropolymerization of aniline and metanilic acid in aqueous HClO4 leads to a copolymer similar to that obtained by direct sulfonation of polyaniline. Characterization by electrochemical and spectroscopic methods (UV -visible, Fourier transform IR and proton NMR) indicated the presence of polyaniline linear chains in which metanilic acid units were inserted as spacers. Elemental analysis showed that the copolymer was 40% doped by the sulfonate side-groups intramolecularly (self-doping) and 20% doped by ClO4 - intermolecularly. The presence of sulfonate functional groups decreased electronic conductivity and increased solubility in alkaline solvents, but the electtrochemical properties remained principally that of polyaniline. © 1993.|
|Source Title:||Journal of Electroanalytical Chemistry|
|Appears in Collections:||Staff Publications|
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