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|Title:||Unexpected coordination difference in geometric-isomerism between N,S- and N,N-heterocyclic carbenes in cyclometallated platinum(ii)|
|Authors:||Yen, S.K. |
|Citation:||Yen, S.K., Young, D.J., Huynh, H.V., Koh, L.L., Hor, T.S.A. (2009). Unexpected coordination difference in geometric-isomerism between N,S- and N,N-heterocyclic carbenes in cyclometallated platinum(ii). Chemical Communications (44) : 6831-6833. ScholarBank@NUS Repository. https://doi.org/10.1039/b914036k|
|Abstract:||The reaction of [PtII(2-phenylpyridine)(acac)] and benzothiazolium bromide yields the N,S-heterocyclic carbene ligand trans to pyridyl while, surprisingly, a very similar N,N-heterocyclic carbene coordinates predominantly trans to the cyclometallated carbon. © 2009 The Royal Society of Chemistry.|
|Source Title:||Chemical Communications|
|Appears in Collections:||Staff Publications|
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