Please use this identifier to cite or link to this item: https://doi.org/10.1039/b914036k
Title: Unexpected coordination difference in geometric-isomerism between N,S- and N,N-heterocyclic carbenes in cyclometallated platinum(ii)
Authors: Yen, S.K. 
Young, D.J.
Huynh, H.V. 
Koh, L.L. 
Hor, T.S.A. 
Issue Date: 2009
Source: Yen, S.K., Young, D.J., Huynh, H.V., Koh, L.L., Hor, T.S.A. (2009). Unexpected coordination difference in geometric-isomerism between N,S- and N,N-heterocyclic carbenes in cyclometallated platinum(ii). Chemical Communications (44) : 6831-6833. ScholarBank@NUS Repository. https://doi.org/10.1039/b914036k
Abstract: The reaction of [PtII(2-phenylpyridine)(acac)] and benzothiazolium bromide yields the N,S-heterocyclic carbene ligand trans to pyridyl while, surprisingly, a very similar N,N-heterocyclic carbene coordinates predominantly trans to the cyclometallated carbon. © 2009 The Royal Society of Chemistry.
Source Title: Chemical Communications
URI: http://scholarbank.nus.edu.sg/handle/10635/90455
ISSN: 13597345
DOI: 10.1039/b914036k
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