Unexpected coordination difference in geometric-isomerism between N,S- and N,N-heterocyclic carbenes in cyclometallated platinum(ii)

Please use this identifier to cite or link to this item: https://doi.org/10.1039/b914036k

Title:	Unexpected coordination difference in geometric-isomerism between N,S- and N,N-heterocyclic carbenes in cyclometallated platinum(ii)
Authors:	Yen, S.K. Young, D.J. Huynh, H.V. Koh, L.L. Hor, T.S.A.
Issue Date:	2009
Citation:	Yen, S.K., Young, D.J., Huynh, H.V., Koh, L.L., Hor, T.S.A. (2009). Unexpected coordination difference in geometric-isomerism between N,S- and N,N-heterocyclic carbenes in cyclometallated platinum(ii). Chemical Communications (44) : 6831-6833. ScholarBank@NUS Repository. https://doi.org/10.1039/b914036k
Abstract:	The reaction of [PtII(2-phenylpyridine)(acac)] and benzothiazolium bromide yields the N,S-heterocyclic carbene ligand trans to pyridyl while, surprisingly, a very similar N,N-heterocyclic carbene coordinates predominantly trans to the cyclometallated carbon. © 2009 The Royal Society of Chemistry.
Source Title:	Chemical Communications
URI:	http://scholarbank.nus.edu.sg/handle/10635/90455
ISSN:	13597345
DOI:	10.1039/b914036k
Appears in Collections:	Staff Publications

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