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https://doi.org/10.1016/j.ica.2008.09.026
| Title: | Synthesis of cyclopentadienyl ruthenium(II) complexes containing tethered functionalities | Authors: | Leong, W.L.J. Garland, M.V. Yoong Goh, L. Kee Leong, W. |
Keywords: | Cyclopentadienyl Ruthenium Synthesis Tethered functionalities |
Issue Date: | 20-Apr-2009 | Citation: | Leong, W.L.J., Garland, M.V., Yoong Goh, L., Kee Leong, W. (2009-04-20). Synthesis of cyclopentadienyl ruthenium(II) complexes containing tethered functionalities. Inorganica Chimica Acta 362 (6) : 2089-2092. ScholarBank@NUS Repository. https://doi.org/10.1016/j.ica.2008.09.026 | Abstract: | The reaction of [C5H4(CH2)nX]Tl (1: n = 2, X = NMe2, OMe, CN; n = 3, X = NMe2) with [(η6-C6H6)RuCl(μ-Cl)]2, 2, afforded the sandwich compounds [{η5-C5H4(CH2)nX}Ru(η6-C6H6)]PF6, 3, and [η5-C5H4(CH2)nX]2Ru, 4. Photolytic cleavage of 3 in acetonitrile afforded the tethered products [{η5:κN-C5H4(CH2)nX}Ru(CH3CN)2]PF6, 5. © 2008 Elsevier B.V. All rights reserved. | Source Title: | Inorganica Chimica Acta | URI: | http://scholarbank.nus.edu.sg/handle/10635/90272 | ISSN: | 00201693 | DOI: | 10.1016/j.ica.2008.09.026 |
| Appears in Collections: | Staff Publications |
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