Please use this identifier to cite or link to this item: https://doi.org/10.1002/adsc.201300717
Title: Mesoporous niobium oxide spheres as an effective catalyst for the transamidation of primary amides with amines
Authors: Ghosh, S.C.
Li, C.C.
Zeng, H.C. 
Ngiam, J.S.Y.
Seayad, A.M.
Chen, A.
Keywords: Amides
Amines
Catalysis
Niobium oxide
Transamidation
Issue Date: 10-Feb-2014
Source: Ghosh, S.C., Li, C.C., Zeng, H.C., Ngiam, J.S.Y., Seayad, A.M., Chen, A. (2014-02-10). Mesoporous niobium oxide spheres as an effective catalyst for the transamidation of primary amides with amines. Advanced Synthesis and Catalysis 356 (2-3) : 475-484. ScholarBank@NUS Repository. https://doi.org/10.1002/adsc.201300717
Abstract: Mesoporous niobium oxide spheres (MNOS), conveniently prepared by a novel antisolvent precipitation approach, have been shown to be an effective catalyst for the transamidation of primary amides with amines. This novel transamidation can be efficiently carried out under solvent-free conditions and is applicable to a wide range of primary amides and amines to provide N-alkyl amides in good to excellent yields. The catalyst is highly stable and reusable. The application of this transamidation reaction has been demonstrated in the synthesis of antidepressant drug moclobemide and other druglike compounds. © 2014 Wiley-VCH Verlag GmbH&Co. KGaA, Weinheim.
Source Title: Advanced Synthesis and Catalysis
URI: http://scholarbank.nus.edu.sg/handle/10635/89384
ISSN: 16154169
DOI: 10.1002/adsc.201300717
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