Please use this identifier to cite or link to this item: https://doi.org/10.1021/jp0741049
Title: Mechanistic study on the bis(p-sulfonatophenyl)phenylphosphine synthesis of monometallic Pt hollow nanoboxes using Ag*-Pt core-shell nanocubes as sacrificial templates
Authors: Tan, Y.-N.
Yang, J.
Lee, J.Y. 
Wang, D.I.C.
Issue Date: 27-Sep-2007
Citation: Tan, Y.-N., Yang, J., Lee, J.Y., Wang, D.I.C. (2007-09-27). Mechanistic study on the bis(p-sulfonatophenyl)phenylphosphine synthesis of monometallic Pt hollow nanoboxes using Ag*-Pt core-shell nanocubes as sacrificial templates. Journal of Physical Chemistry C 111 (38) : 14084-14090. ScholarBank@NUS Repository. https://doi.org/10.1021/jp0741049
Abstract: We report herewith a simple and effective method for the preparation of anisotropic Ag*-Pt core-shell nanocubes and Pt nanoboxes. The core-shell nanocubes were first synthesized by the coreduction of Ag + and PtCl 6 2- and then treated in a bis-(p-sulfonatophenyl)- phenylphosphine (BSPP) solution to remove the core materials. We found that BSPP, in addition to being an effective silver oxidant, was also a good solubilizer for AgCl nanoparticles at room temperature. This allowed us to prepare phase-pure Pt nanoboxes from the as-synthesized Ag*-Pt nanocubes using a greatly simplified posttreatment for AgCl, a reaction byproduct and known impurity in the synthesis of hollow nanostructures by the replacement reaction approach (Ag* is used here to denote nanocomposites of Ag and AgCl). We also showed that AgCl functioned as a removal template in enabling a shape-controlled synthesis of the nanostructures. © 2007 American Chemical Society.
Source Title: Journal of Physical Chemistry C
URI: http://scholarbank.nus.edu.sg/handle/10635/89373
ISSN: 19327447
DOI: 10.1021/jp0741049
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