Please use this identifier to cite or link to this item: https://doi.org/10.1002/chem.201102295
Title: Fluorinated metal-organic frameworks: Advantageous for higher H 2 and CO 2 adsorption or not?
Authors: Pachfule, P.
Chen, Y.
Jiang, J. 
Banerjee, R.
Keywords: cobalt
fluorine
hydrogen storage
metal-organic frameworks
microporous materials
X-ray diffraction
Issue Date: 9-Jan-2012
Citation: Pachfule, P., Chen, Y., Jiang, J., Banerjee, R. (2012-01-09). Fluorinated metal-organic frameworks: Advantageous for higher H 2 and CO 2 adsorption or not?. Chemistry - A European Journal 18 (2) : 688-694. ScholarBank@NUS Repository. https://doi.org/10.1002/chem.201102295
Abstract: The synthesis, structure, and gas adsorption properties of three new metal-organic frameworks (MOFs) designed from isonicotinic acid (INA) and its fluorinated analogue 3-fluoroisonicotinic acid (FINA) along with Co II as the metal center have been reported. Co-INA-1 ([Co 3(INA) 4(O)(C 2H 5OH) 3][NO 3]̇C 2H 5OḢ3 H 2O; INA=isonicotinic acid) and Co-INA-2 ([Co(INA) 2]̇DMF) are structural isomers as are Co-FINA-1 ([Co 3(FINA) 4(O)(C 2H 5OH) 2]̇H 2O; FINA=3-fluoroisonicotinic acid) and Co-FINA-2 ([Co(FINA) 2]̇H 2O), but the most important thing to note here is that Co-INA-1 and Co-FINA-1 are isostructural as are Co-INA-2 and Co-FINA-2. The effect of partial introduction of fluorine atoms into the framework on the gas uptake properties of MOFs having similar structures has been analyzed experimentally and computationally in isostructural MOFs. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Source Title: Chemistry - A European Journal
URI: http://scholarbank.nus.edu.sg/handle/10635/88937
ISSN: 09476539
DOI: 10.1002/chem.201102295
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

56
checked on May 21, 2018

WEB OF SCIENCETM
Citations

56
checked on Apr 25, 2018

Page view(s)

47
checked on May 25, 2018

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.