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|Title:||Experimental and computational approach of understanding the gas adsorption in amino functionalized interpenetrated metal organic frameworks (MOFs)|
|Citation:||Pachfule, P., Chen, Y., Jiang, J., Banerjee, R. (2011-11-28). Experimental and computational approach of understanding the gas adsorption in amino functionalized interpenetrated metal organic frameworks (MOFs). Journal of Materials Chemistry 21 (44) : 17737-17745. ScholarBank@NUS Repository. https://doi.org/10.1039/c1jm13762j|
|Abstract:||Two isostructural, three dimensional, interpenetrated, amino (-NH 2) functionalized Metal Organic Frameworks [Cd(ANIC)2] (Cd-ANIC-1) and [Co(ANIC)2] (Co-ANIC-1) with amine-lined pores have been reported. The framework adopts dia topology with interpenetration. Cd-ANIC-1 and Co-ANIC-1 show high CO2 (273 K) and H2 (77 K) uptake due to the presence of free -NH2 groups and framework interpenetration. The effect of interpenetration and amino functionalization on gas uptake properties of MOFs has been analysed experimentally and computationally, in the isostructural MOFs Cd-ANIC-1 and Co-ANIC-1. © 2011 The Royal Society of Chemistry.|
|Source Title:||Journal of Materials Chemistry|
|Appears in Collections:||Staff Publications|
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