Please use this identifier to cite or link to this item:
|Title:||PbS/CdS-sensitized mesoscopic SnO 2 solar cells for enhanced infrared light harnessing|
|Citation:||Hossain, M.A., Koh, Z.Y., Wang, Q. (2012-05-28). PbS/CdS-sensitized mesoscopic SnO 2 solar cells for enhanced infrared light harnessing. Physical Chemistry Chemical Physics 14 (20) : 7367-7374. ScholarBank@NUS Repository. https://doi.org/10.1039/c2cp40551b|
|Abstract:||Metal oxide semiconductors with lower lying conduction band minimum and superior electron mobility are essential for efficient charge separation and collection in PbS-sensitized solar cells. In the present study, mesoscopic SnO 2 was investigated as an alternative photoanode to the commonly used TiO 2 and examined comprehensively in PbS-sensitized liquid junction solar cells. To exploit the capability of PbS in an optimized structure, cascaded nPbS/nCdS and alternate n(PbS/CdS) layers deposited by a successive ionic layer adsorption and reaction method were systematically scrutinized. It was observed that the surface of SnO 2 has greater affinity to the growth of PbS compared with TiO 2, giving rise to much enhanced light absorption. In addition, the deposition of a CdS buffer layer and a ZnS passivation layer before and after a PbS layer was found to be beneficial for efficient charge separation. Under optimized conditions, cascaded PbS/CdS-sensitized SnO 2 exhibited an unprecedented photocurrent density of 17.38 mA cm -2 with pronounced infrared light harvesting extending beyond 1100 nm, and a power conversion efficiency of 2.23% under AM 1.5, 1 sun illumination. In comparison, TiO 2 cells fabricated under similar conditions showed much inferior performance owing to the less efficient light harnessing of long wavelength photons. We anticipate that the systematic study of PbS-sensitized solar cells utilizing different metal oxide semiconductors as electron transporters would provide useful insights and promote the development of semiconductor-sensitized mesoscopic solar cells employing panchromatic sensitizers. © 2012 the Owner Societies.|
|Source Title:||Physical Chemistry Chemical Physics|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Sep 22, 2018
WEB OF SCIENCETM
checked on Sep 12, 2018
checked on Aug 10, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.