Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.intermet.2011.10.013
Title: Thermal oxidation effect on corrosion behavior of Zr 46Cu 37.6Ag 8.4Al 8 bulk metallic glass
Authors: Nie, X.P.
Yang, X.H.
Ma, Y.
Chen, L.Y.
Yeap, K.B.
Zeng, K.Y. 
Li, D.
Pan, J.S.
Wang, X.D.
Cao, Q.P.
Ding, S.Q.
Jiang, J.Z.
Keywords: A. Intermetallics, miscellaneous
B. Corrosion
B. Oxidation
F. Corrosion behavior
F. Electron microscopy, scanning
Issue Date: Mar-2012
Citation: Nie, X.P., Yang, X.H., Ma, Y., Chen, L.Y., Yeap, K.B., Zeng, K.Y., Li, D., Pan, J.S., Wang, X.D., Cao, Q.P., Ding, S.Q., Jiang, J.Z. (2012-03). Thermal oxidation effect on corrosion behavior of Zr 46Cu 37.6Ag 8.4Al 8 bulk metallic glass. Intermetallics 22 : 84-91. ScholarBank@NUS Repository. https://doi.org/10.1016/j.intermet.2011.10.013
Abstract: Oxide films of 0.72 μm and 1.80 μm were prepared by thermal oxidation treatments at 441 K and 609 K respectively. The oxidation kinetics of the Zr 46Cu 37.6Ag 8.4Al 8 bulk metallic glass has been investigated. The outermost surface of the oxide film formed at 609 k is Cu 2O and Al 2O 3-enriched but ZrO 2-depleted. A ZrO 2-enriched oxide layer is detected existing at 150-260 nm of the oxide film. The surface oxidation state sheds great influence on the corrosion behavior of Zr-based BMG. The oxide film can hinder the initial electrodissolution processes during polarization in 0.5 M H 2SO 4 + 0.01 M NaCl solution. The special structure and composition distribution of the oxide film lead to the modification of the BMG's corrosion behavior. © 2011 Elsevier Ltd. All rights reserved.
Source Title: Intermetallics
URI: http://scholarbank.nus.edu.sg/handle/10635/85790
ISSN: 09669795
DOI: 10.1016/j.intermet.2011.10.013
Appears in Collections:Staff Publications

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