Please use this identifier to cite or link to this item:
|Title:||Sol-gel derived nanostructured Li2MnSiO4/C cathode with high storage capacity|
|Keywords:||Flat charge/discharge plateau|
|Citation:||Devaraj, S., Kuezma, M., Ng, C.T., Balaya, P. (2013). Sol-gel derived nanostructured Li2MnSiO4/C cathode with high storage capacity. Electrochimica Acta 102 : 290-298. ScholarBank@NUS Repository. https://doi.org/10.1016/j.electacta.2013.04.009|
|Abstract:||Carbon-coated, nanostructured Li2MnSiO4 (LMS/C) was synthesized by sol-gel method using a chelating carbonizing source, Glucono-1,5-lactone (GAL). Powder X-ray diffraction studies confirmed nominally pure phase formation. SEM and TEM studies revealed that LMS/C is comprised of particles of less than 50 nm in diameter with a thin film of 1-5 nm amorphous carbon coating. Elemental mapping demonstrated a homogenous distribution of carbon throughout LMS/C. Besides carbon coating, GAL promotes phase purity and reduces particle agglomeration during annealing. Raman spectroscopic study revealed that the carbon formed in LMS/C nanocomposite is mostly amorphous. The electrochemical performance of LMS/C was evaluated by galvanostatic charge/discharge cycles at various C-rates. We report here a well-defined, flat charge/discharge plateau for LMS/C with extraction/insertion of 1.5 Li +-ion per formula unit at room temperature in a narrow potential window 2.0-4.5 V at various current rates. Together with ex situ XPS studies carried out at various states of charge we confirm that the charge and discharge plateaus are associated with the redox chemistry of manganese. LMS/C exhibits a stable discharge capacity for about 10 cycles at various C-rates. However, the capacity fades gradually after 11 cycles at all C-rates. An ex situ XRD study confirmed that the phase was retained up to 10 cycles. The stable cycle-life and the improvement in observed electrochemical performance is attributed to the phase retention in LMS/C nanocomposite. © 2013 Elsevier Ltd. All rights reserved.|
|Source Title:||Electrochimica Acta|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Nov 17, 2018
WEB OF SCIENCETM
checked on Oct 16, 2018
checked on Nov 2, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.