Please use this identifier to cite or link to this item: https://doi.org/10.1039/c2cs35234f
Title: Solid-state reactivity and structural transformations involving coordination polymers
Authors: Kole, G.K.
Vittal, J.J. 
Issue Date: 21-Feb-2013
Citation: Kole, G.K., Vittal, J.J. (2013-02-21). Solid-state reactivity and structural transformations involving coordination polymers. Chemical Society Reviews 42 (4) : 1755-1775. ScholarBank@NUS Repository. https://doi.org/10.1039/c2cs35234f
Abstract: This tutorial review discusses recent literature on coordination polymers and metal-organic frameworks (MOFs) that exhibit solid-state reactivity and structural transformation under various experimental conditions. Removal or exchange of solvents and guest molecules, exposure to reactive vapours, and external stimuli such as heat, light or mechanochemical force cause such structural transformations and these are often manifested by various physical properties such as colour, magnetism, luminescence, chirality, porosity, etc. due to change in coordination number and geometry, dimensionality, interpenetration, etc. More drastic transformations related to the exchange of metal ions, pillar ligands and insertion of additional ligands between the layers have also been demonstrated. The vast area of dynamic behaviour of coordination polymers and their stimuli-responsive properties have also been addressed briefly. © 2013 The Royal Society of Chemistry.
Source Title: Chemical Society Reviews
URI: http://scholarbank.nus.edu.sg/handle/10635/77654
ISSN: 03060012
DOI: 10.1039/c2cs35234f
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

279
checked on Dec 18, 2018

WEB OF SCIENCETM
Citations

259
checked on Dec 18, 2018

Page view(s)

31
checked on Nov 2, 2018

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.