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https://doi.org/10.1016/j.cplett.2003.09.016
| Title: | Vibrational spectroscopy and 266 nm photochemistry of NCNCS and CNCN | Authors: | Li, P. Wong, L.K. Fan, W.Y. |
Issue Date: | 13-Oct-2003 | Citation: | Li, P., Wong, L.K., Fan, W.Y. (2003-10-13). Vibrational spectroscopy and 266 nm photochemistry of NCNCS and CNCN. Chemical Physics Letters 380 (1-2) : 117-122. ScholarBank@NUS Repository. https://doi.org/10.1016/j.cplett.2003.09.016 | Abstract: | The 266 nm pulsed laser photodissociation of cyanogen isothiocyanate (NCNCS) in a static cell was investigated leading to the detection of the gas phase Raman spectra of NCNCS and its photolysis product, isocyanogen (CNCN). The strongest Raman-active vibrational bands for both molecules were recorded using Coherent Anti-Stokes Raman Scattering (CARS) Spectroscopy around 5 μm. Direct C-S bond cleavage as a result of the photodissociation of NCNCS appears to be the most likely route for the generation of CNCN from NCNCS. © 2003 Elsevier B.V. All rights reserved. | Source Title: | Chemical Physics Letters | URI: | http://scholarbank.nus.edu.sg/handle/10635/77352 | ISSN: | 00092614 | DOI: | 10.1016/j.cplett.2003.09.016 |
| Appears in Collections: | Staff Publications |
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