Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/77082
Title: Studies towards total synthesis of antillatoxin: Indium-mediated allylation reaction of carbonyl compounds with secondary allylic bromide in aqueos media
Authors: Loh, T.-P. 
Song, H.-Y. 
Keywords: Allylation reaction
Antillatoxin
Aqueous media
Homoallylic alcohols
Indium
Issue Date: 2002
Citation: Loh, T.-P.,Song, H.-Y. (2002). Studies towards total synthesis of antillatoxin: Indium-mediated allylation reaction of carbonyl compounds with secondary allylic bromide in aqueos media. Synlett (12) : 2119-2121. ScholarBank@NUS Repository.
Abstract: We have established a new reaction condition for the indium-mediated allylation of an unreactive secondary allylic bromide with aldehydes in aqueous media to afford the corresponding homoallylic alcohols in high yields and syn diastereoselectivity. Furthermore, it has provided an easy entry to the key intermediate for the total synthesis of antillatoxin under mild and environment profitable conditions.
Source Title: Synlett
URI: http://scholarbank.nus.edu.sg/handle/10635/77082
ISSN: 09365214
Appears in Collections:Staff Publications

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