Structure of undecacarbonyl[tris(pentafluorophenyl)phosphine]-triangulo- triosmium, a substituted osmium cluster containing a fluorinated triphenylphosphine ligand.

Please use this identifier to cite or link to this item: https://doi.org/10.1107/S0108270189003719

Title:	Structure of undecacarbonyl[tris(pentafluorophenyl)phosphine]-triangulo- triosmium, a substituted osmium cluster containing a fluorinated triphenylphosphine ligand.
Authors:	Ang, H.G. Kwik, W.L. Leong, W.K. Potenza, J.A.
Issue Date:	15-Nov-1989
Citation:	Ang, H.G., Kwik, W.L., Leong, W.K., Potenza, J.A. (1989-11-15). Structure of undecacarbonyl[tris(pentafluorophenyl)phosphine]-triangulo- triosmium, a substituted osmium cluster containing a fluorinated triphenylphosphine ligand.. Acta Crystallographica, Section C: Crystal Structure Communications 45 : Pt 11/-. ScholarBank@NUS Repository. https://doi.org/10.1107/S0108270189003719
Abstract:	[Os3(CO)11[P(C6F5)3]], Mr = 1410.87, monoclinic, P2(1)/n, a = 19.058 (1), b = 9.109 (1), c = 20.424 (2) A, beta = 105.53 (1) degree, V = 3416 (1) A3, Z = 4, Dm = 2.74 (2), Dx = 2.743 g cm-3, mu(Mo K alpha, lambda = 0.71073 A) = 113.3 cm-1, F(000) = 2560, T = 297 (1) K, RF = 0.022 for 3529 reflections. The Os atoms form an approximate isosceles triangle. Each Os atom exhibits a distorted octahedral coordination geometry. The carbonyl groups are all terminal and the bulky phosphine ligand is coordinated equatorially.
Source Title:	Acta Crystallographica, Section C: Crystal Structure Communications
URI:	http://scholarbank.nus.edu.sg/handle/10635/77069
ISSN:	01082701
DOI:	10.1107/S0108270189003719
Appears in Collections:	Staff Publications

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