Please use this identifier to cite or link to this item: https://doi.org/10.1002/(SICI)1522-2683(19990801)20:12<2475
Title: Simultaneous analysis of lead, mercury and selenium species by capillary electrophoresis with combined ethylenediaminetetraacetic acid complexation and field-amplified stacking injection
Authors: Liu, W.
Lee, H.K. 
Keywords: Capillary electrophoresis
Complexation
Ethylenediaminetetraacetic acid
Speciation analysis
Stacking injection
Issue Date: 1999
Citation: Liu, W.,Lee, H.K. (1999). Simultaneous analysis of lead, mercury and selenium species by capillary electrophoresis with combined ethylenediaminetetraacetic acid complexation and field-amplified stacking injection. Electrophoresis 20 (12) : 2475-2483. ScholarBank@NUS Repository. https://doi.org/10.1002/(SICI)1522-2683(19990801)20:12<2475
Abstract: In this study, speciation analysis was carried out for multispecies of lead, mercury and selenium by capillary electrophoresis (CE) with combined complexation and field-amplified stacking injection (FASI). Ethylenediaminetetraacetic acid (EDTA) was added to the sample mixture to form UV-absorbing complexes with the analytes, thus enabling direct UV detection. It was also used in the running electrolyte to improve resolution. Under optimal conditions, ten analytes were baseline-separated within 20 min. The influence of operational conditions (pH, EDTA concentration, sodium dodecyl sulfate concentration) on the electrophoretic behavior of the species was studied. The analyte-related parameters were calculated based on the migration equation. Enhancement of detection, up to 1700-fold, was achieved for the charged complexes with FASI, and sub-ng/mL detection limits were obtained. The performance of this method was compared with high-performance liquid chromatography, gas chromatography and other CE procedures.
Source Title: Electrophoresis
URI: http://scholarbank.nus.edu.sg/handle/10635/76974
ISSN: 01730835
DOI: 10.1002/(SICI)1522-2683(19990801)20:12<2475
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