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|Title:||Selective formation of cumulative double bonds (C=C=N) in the attachment of multifunctional molecules on Si(111)-7 × 7|
|Source:||Tao, F., Chen, X.F., Wang, Z.H., Xu, G.Q. (2002-06-19). Selective formation of cumulative double bonds (C=C=N) in the attachment of multifunctional molecules on Si(111)-7 × 7. Journal of the American Chemical Society 124 (24) : 7170-7180. ScholarBank@NUS Repository. https://doi.org/10.1021/ja012563w|
|Abstract:||The cumulative double bond (C=C=N), an important intermediate in synthetic organic chemistry, was successfully prepared via the selective attachment of acrylonitrile to Si(111)-7 x 7. The covalent binding of acrylonitrile on Si(111)-7 x 7 was studied using high-resolution electron energy loss spectroscopy (HREELS), X-ray photoelectron spectroscopy (XPS), ultraviolet photoelectron spectroscopy (UPS), scanning tunneling microscopy (STM) and DFT calculations. The observation of the characteristic vibrational modes and electronic structures of the C=C=N group in the surface species demonstrates the [4 + 2]-like cycloaddition occurring between the terminal C and N atoms of acrylonitrile and the neighboring adatomrest atom pair, consistent with the prediction of DFT calculations. STM studies further show the preferential binding of acrylonitrile on the center adatom sites of faulted halves of Si(111)-7 x 7 unit cells.|
|Source Title:||Journal of the American Chemical Society|
|Appears in Collections:||Staff Publications|
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