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|Title:||Primary amino acids: Privileged catalysts in enantioselective organocatalysis|
|Authors:||Xu, L.-W. |
|Citation:||Xu, L.-W., Lu, Y. (2008). Primary amino acids: Privileged catalysts in enantioselective organocatalysis. Organic and Biomolecular Chemistry 6 (12) : 2047-2053. ScholarBank@NUS Repository. https://doi.org/10.1039/b803116a|
|Abstract:||Despite the recent spectacular advances in asymmetric organocatalysis, proline and its analogues have been predominantly employed as organocatalysts in reactions utilizing enamine intermediates. Recent studies of enantioselective organocatalytic reactions promoted by primary amino acids and their derivatives are described in this account. The primary amino functions, rather than the secondary pyrrolidine moiety, have been shown to provide unique reactivity and stereoselectivity in asymmetric aldol and Mannich reactions. © The Royal Society of Chemistry 2008.|
|Source Title:||Organic and Biomolecular Chemistry|
|Appears in Collections:||Staff Publications|
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