Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.tetlet.2008.09.025
Title: Noyori's Ts-DPEN ligand: an efficient bifunctional primary amine-based organocatalyst in enantio- and diastereoselective Michael addition of 1,3-dicarbonyl indane compounds to nitroolefins
Authors: Ju, Y.-D.
Xu, L.-W.
Li, L.
Lai, G.-Q.
Qiu, H.-Y.
Jiang, J.-X.
Lu, Y. 
Keywords: Dual activation
Michael addition
Organocatalysis
Primary amine
Issue Date: 24-Nov-2008
Citation: Ju, Y.-D., Xu, L.-W., Li, L., Lai, G.-Q., Qiu, H.-Y., Jiang, J.-X., Lu, Y. (2008-11-24). Noyori's Ts-DPEN ligand: an efficient bifunctional primary amine-based organocatalyst in enantio- and diastereoselective Michael addition of 1,3-dicarbonyl indane compounds to nitroolefins. Tetrahedron Letters 49 (48) : 6773-6777. ScholarBank@NUS Repository. https://doi.org/10.1016/j.tetlet.2008.09.025
Abstract: Noyori's Ts-DPEN ligand bearing an amino sulfonamide moiety and with a primary amino group on a chiral scaffold was found to be a simple and efficient bifunctional organocatalyst for the asymmetric Michael addition of 1,3-dicarbonyl compounds to nitroolefins, which gave highly functional Michael adduct with quaternary stereocenters in good enantioselectivities (up to 84%ee) and dr (up to 5.7:1 dr). © 2008.
Source Title: Tetrahedron Letters
URI: http://scholarbank.nus.edu.sg/handle/10635/76656
ISSN: 00404039
DOI: 10.1016/j.tetlet.2008.09.025
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