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|Title:||Mono-, di-, and trinitrenes in the pyridine series|
|Citation:||Chapyshev, S.V., Kuhn, A., Wong, M.W., Wentrup, C. (2000-03-01). Mono-, di-, and trinitrenes in the pyridine series. Journal of the American Chemical Society 122 (8) : 1572-1579. ScholarBank@NUS Repository. https://doi.org/10.1021/ja9931067|
|Abstract:||Tetrafluoro- and tetrachloro-4-pyridylnitrenes are formed on matrix photolysis of the corresponding azides and are found to be highly photostable in low-temperature matrices in contrast to nonhalogenated 4-pyridylnitrene. Matrix photolysis of 3,5-dichloro- or 3-chloro-5-cyano-2,4,6- triazidopyridines leads in rapid succession to mono-, di-, and trinitrenopyridines. The corresponding 3,5-dicyano-2,4,6-triazidopyridine does not produce an identifiable trinitrene. All the above species were identified by evaluation of the temporal evolution of the Ar matrix IR spectra and excellent agreement with DFT-calculated data.|
|Source Title:||Journal of the American Chemical Society|
|Appears in Collections:||Staff Publications|
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