Please use this identifier to cite or link to this item: https://doi.org/10.1021/ja9931067
Title: Mono-, di-, and trinitrenes in the pyridine series
Authors: Chapyshev, S.V.
Kuhn, A.
Wong, M.W. 
Wentrup, C.
Issue Date: 1-Mar-2000
Citation: Chapyshev, S.V., Kuhn, A., Wong, M.W., Wentrup, C. (2000-03-01). Mono-, di-, and trinitrenes in the pyridine series. Journal of the American Chemical Society 122 (8) : 1572-1579. ScholarBank@NUS Repository. https://doi.org/10.1021/ja9931067
Abstract: Tetrafluoro- and tetrachloro-4-pyridylnitrenes are formed on matrix photolysis of the corresponding azides and are found to be highly photostable in low-temperature matrices in contrast to nonhalogenated 4-pyridylnitrene. Matrix photolysis of 3,5-dichloro- or 3-chloro-5-cyano-2,4,6- triazidopyridines leads in rapid succession to mono-, di-, and trinitrenopyridines. The corresponding 3,5-dicyano-2,4,6-triazidopyridine does not produce an identifiable trinitrene. All the above species were identified by evaluation of the temporal evolution of the Ar matrix IR spectra and excellent agreement with DFT-calculated data.
Source Title: Journal of the American Chemical Society
URI: http://scholarbank.nus.edu.sg/handle/10635/76593
ISSN: 00027863
DOI: 10.1021/ja9931067
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