Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/76542
Title: Miscibility of poly(2-fluoroethyl methacrylate) and poly(1,1,1,3,3,3-hexafluoroisopropyl methacrylate) with various polymethacrylates
Authors: Peng, J.
Goh, S.H. 
Lee, S.Y. 
Siow, K.S. 
Keywords: fluorine-containing polymers
miscibility
polymethacrylates
Issue Date: Mar-1994
Source: Peng, J.,Goh, S.H.,Lee, S.Y.,Siow, K.S. (1994-03). Miscibility of poly(2-fluoroethyl methacrylate) and poly(1,1,1,3,3,3-hexafluoroisopropyl methacrylate) with various polymethacrylates. Polymer 35 (7) : 1482-1486. ScholarBank@NUS Repository.
Abstract: The miscibility behaviour of poly(2-fluoroethyl methacrylate) (P2FEMA) and poly(1,1,1,3,3,3-hexafluoroisopropyl methacrylate) (PHFPMA) with various polymethacrylates was studied by differential scanning calorimetry and for lower critical solution temperature (LCST) behaviour. Both P2FEMA and PHFPMA are miscible with poly(methyl methacrylate) (PMMA), poly(ethyl methacrylate) (PEMA) and poly(tetrahydrofurfuryl methacrylate) (PTHFMA), but are immiscible with poly(n-propyl methacrylate) (PnPMA), poly(isopropyl methacrylate) (PiPMA), poly(n-butyl methacrylate) (PnBMA) and poly(cyclohexyl methacrylate) (PCHMA). Phase separation could be induced by heating for blends of P2FEMA with PMMA and PEMA. For PHFPMA, only PHFPMA/PEMA blends showed LCST behaviour. The miscibility behaviour of P2FEMA and PHFPMA is similar to that of poly(2-chloroethyl methacrylate). © 1994.
Source Title: Polymer
URI: http://scholarbank.nus.edu.sg/handle/10635/76542
ISSN: 00323861
Appears in Collections:Staff Publications

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