Indium-mediated allylation of carbonyl compounds with an allylic bromide in aqueous media: Anomalous syn-diastereoselectivity regardless of allylic bromide geometry

Please use this identifier to cite or link to this item: https://doi.org/10.1016/S0040-4039(02)02773-9

Title:	Indium-mediated allylation of carbonyl compounds with an allylic bromide in aqueous media: Anomalous syn-diastereoselectivity regardless of allylic bromide geometry
Authors:	Loh, T.-P. Yin, Z. Song, H.-Y. Tan, K.-L.
Issue Date:	27-Jan-2003
Citation:	Loh, T.-P., Yin, Z., Song, H.-Y., Tan, K.-L. (2003-01-27). Indium-mediated allylation of carbonyl compounds with an allylic bromide in aqueous media: Anomalous syn-diastereoselectivity regardless of allylic bromide geometry. Tetrahedron Letters 44 (5) : 911-914. ScholarBank@NUS Repository. https://doi.org/10.1016/S0040-4039(02)02773-9
Abstract:	Anomalous syn-diastereoselectivity of indium-mediated coupling of aldehydes with bromides Z-3b and E-3b is reported. The reaction afforded high syn selectivity regardless of the allylic bromide geometry. Preliminary studies on the enantioselective indium-mediated allylation were attempted and found to give the desired products in moderate yield with high syn selectivity and enantioselectivity. © 2003 Elsevier Science Ltd. All rights reserved.
Source Title:	Tetrahedron Letters
URI:	http://scholarbank.nus.edu.sg/handle/10635/76371
ISSN:	00404039
DOI:	10.1016/S0040-4039(02)02773-9
Appears in Collections:	Staff Publications

There are no files associated with this item.

Check