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|Title:||Electron-deficient triphenylene and trinaphthylene carboximides|
|Authors:||Yin, J. |
|Source:||Yin, J., Qu, H., Zhang, K., Luo, J., Zhang, X., Chi, C., Wu, J. (2009-07-16). Electron-deficient triphenylene and trinaphthylene carboximides. Organic Letters 11 (14) : 3028-3031. ScholarBank@NUS Repository. https://doi.org/10.1021/ol901041n|
|Abstract:||A series of triphenylene and trinaphthylene carboximides were synthesized mainly through Diels-Alder reactions between the in situ generated radialenes and N-alkylmaleimides. High electron affinity was obtained due to the attachment of electron-withdrawing carboximide groups. These disklike molecules can assemble into one-dimensional columnar structures in solid state and their mesophase properties were characterized by DSC, POM, and X-ray diffraction. Long-range ordered columnar phase was observed, qualifying them as potential n-type semiconductors in electronic devices. © 2009 American Chemical Society.|
|Source Title:||Organic Letters|
|Appears in Collections:||Staff Publications|
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