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|Title:||Covalent attachment of acetonitrile on Si(100) through Si-C and Si-N linkages|
|Citation:||Tao, F., Wang, Z.H., Qiao, M.H., Liu, Q., Sim, W.S., Xu, G.Q. (2001-11-08). Covalent attachment of acetonitrile on Si(100) through Si-C and Si-N linkages. Journal of Chemical Physics 115 (18) : 8563-8569. ScholarBank@NUS Repository. https://doi.org/10.1063/1.1410388|
|Abstract:||An analysis of covalent binding and adsorption states of acetonitrile on Si(100) was performed. For this analysis temperature programmed desorption (TPD), X-ray photoelectron spectroscopy (XPS), high-resolution electron energy loss spectroscopy (HREELS) and density functional theory (DFT) were used. The results showed that acetonitrile chemisorbs on Si(100) in a side-on di-σ binding configuration forming Si-C and Si-N σ bonds.|
|Source Title:||Journal of Chemical Physics|
|Appears in Collections:||Staff Publications|
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