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|Title:||Asymmetric synthesis of 2-Aryl-2,3-dihydro-4-quinolones via bifunctional thiourea-mediated intramolecular cyclization|
|Citation:||Liu, X., Lu, Y. (2010-12-03). Asymmetric synthesis of 2-Aryl-2,3-dihydro-4-quinolones via bifunctional thiourea-mediated intramolecular cyclization. Organic Letters 12 (23) : 5592-5595. ScholarBank@NUS Repository. https://doi.org/10.1021/ol102519z|
|Abstract:||A novel asymmetric preparation of optically enriched 2-aryl-2,3- dihydroquinolin-4(1H)-ones has been developed. By installing a sulfonyl group on the nitrogen of the anilines and an ester function on the unsaturated ketones, an intramolecular organocatalytic cyclization took place readily in a stereoselective manner, resulting in the formation of dihydroquinolones with high enantioselectivity. © 2010 American Chemical Society.|
|Source Title:||Organic Letters|
|Appears in Collections:||Staff Publications|
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