A P-O chelation with palladium: Toward understanding of the stereochemistry of an optically active sulfinyl-substituted phosphine with five stereogenic centres

Please use this identifier to cite or link to this item: https://doi.org/10.1016/0957-4166(96)00005-5

Title:	A P-O chelation with palladium: Toward understanding of the stereochemistry of an optically active sulfinyl-substituted phosphine with five stereogenic centres
Authors:	Siah, S.-Y. Leung, P.-H. Mok, K.F. Drew, M.G.B.
Issue Date:	Feb-1996
Citation:	Siah, S.-Y., Leung, P.-H., Mok, K.F., Drew, M.G.B. (1996-02). A P-O chelation with palladium: Toward understanding of the stereochemistry of an optically active sulfinyl-substituted phosphine with five stereogenic centres. Tetrahedron Asymmetry 7 (2) : 357-360. ScholarBank@NUS Repository. https://doi.org/10.1016/0957-4166(96)00005-5
Abstract:	The enantiomerically pure Diels-Alder product (-)-1 was subjected to chloride abstraction to give the title complex (-)-2. The absolute stereochemistry of the optically active ligand, 2,3-dimethyl-7-phenyl-5-vinylsulfinyl-7-phosphabicyclo[2.2.1]hept-2-en e 3, in (-)-2 was confirmed by crystallographic analysis. 3 formed a six-membered P-O chelate with the [(R)-1-[1-(dimethylamino)ethyl]-2-naphthalenyl-C,N]palladium(II) unit.
Source Title:	Tetrahedron Asymmetry
URI:	http://scholarbank.nus.edu.sg/handle/10635/75469
ISSN:	09574166
DOI:	10.1016/0957-4166(96)00005-5
Appears in Collections:	Staff Publications

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