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|Title:||A P-O chelation with palladium: Toward understanding of the stereochemistry of an optically active sulfinyl-substituted phosphine with five stereogenic centres|
|Citation:||Siah, S.-Y., Leung, P.-H., Mok, K.F., Drew, M.G.B. (1996-02). A P-O chelation with palladium: Toward understanding of the stereochemistry of an optically active sulfinyl-substituted phosphine with five stereogenic centres. Tetrahedron Asymmetry 7 (2) : 357-360. ScholarBank@NUS Repository. https://doi.org/10.1016/0957-4166(96)00005-5|
|Abstract:||The enantiomerically pure Diels-Alder product (-)-1 was subjected to chloride abstraction to give the title complex (-)-2. The absolute stereochemistry of the optically active ligand, 2,3-dimethyl-7-phenyl-5-vinylsulfinyl-7-phosphabicyclo[2.2.1]hept-2-en e 3, in (-)-2 was confirmed by crystallographic analysis. 3 formed a six-membered P-O chelate with the [(R)-1-[1-(dimethylamino)ethyl]-2-naphthalenyl-C,N]palladium(II) unit.|
|Source Title:||Tetrahedron Asymmetry|
|Appears in Collections:||Staff Publications|
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