Please use this identifier to cite or link to this item:
|Title:||The synergistic effects of propargyl alcohol and potassium iodide on the inhibition of mild steel in 0.5 M sulfuric acid solution|
|Citation:||Feng, Y., Siow, K.S., Teo, W.K., Hsieh, A.K. (1999-05-01). The synergistic effects of propargyl alcohol and potassium iodide on the inhibition of mild steel in 0.5 M sulfuric acid solution. Corrosion Science 41 (5) : 829-852. ScholarBank@NUS Repository. https://doi.org/10.1016/S0010-938X(98)00144-9|
|Abstract:||The corrosion and inhibition behaviors of mild steel in aerated sulphuric acid in the presence of propargyl alcohol (PA) and potassium iodide (KI) were investigated using electrochemical methods. It was found that the inhibition efficiency increased with PA concentration, but the potential of unpolarizability (E(u)), which indicates the commencement of desorption of adsorbed propargyl alcohol on the electrode, remained unchanged with increasing PA concentration. The addition of potassium iodide in the solution increased the value of E(u). A synergistic effect was observed between KI and PA with an optimum mass ratio of [PA]/[KI]=1/1. The experimental results suggest that the presence of iodide ions in the solutions stabilized the adsorption of PA molecules on the metal surfaces and, therefore, improved the inhibition efficiency of PA. In the solutions containing propargyl alcohol (PA), the E(u) values remained unchanged with increasing immersion times, indicating that there was less possibility of polymerization of PA molecules. An adsorption mechanism was favored for the inhibition of PA.|
|Source Title:||Corrosion Science|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Jun 17, 2018
WEB OF SCIENCETM
checked on May 16, 2018
checked on Jun 15, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.