Please use this identifier to cite or link to this item: https://doi.org/10.1246/bcsj.72.1941
Title: Synthesis and characterization of a novel green photoluminescent silicon-containing poly(p-phenylenevinylene)
Authors: Chen, Z.-K. 
Wang, L.-H. 
Kang, E.-T. 
Lai, Y.-H. 
Huang, W. 
Issue Date: Aug-1999
Source: Chen, Z.-K.,Wang, L.-H.,Kang, E.-T.,Lai, Y.-H.,Huang, W. (1999-08). Synthesis and characterization of a novel green photoluminescent silicon-containing poly(p-phenylenevinylene). Bulletin of the Chemical Society of Japan 72 (8) : 1941-1946. ScholarBank@NUS Repository. https://doi.org/10.1246/bcsj.72.1941
Abstract: A novel solution processable photoluminescent polymer containing silyl groups has been successfully synthesized through a polycondensation reaction. The polymer was characterized through FT-IR, NMR, UV-vis spectroscopy, photoluminescent spectroscopy (PL), elemental analysis and cyclic voltammetry (CV). A TGA analysis shows that the polymer is stable up to 300 °C both in air and in nitrogen. The UV-vis absorption spectra for both the solution and film samples are very similar. The band gap obtained from the optical spectra is 2.53 eV. The maximum emissions of photoluminescence are at 494 and 507 nm for the solution and film samples, respectively. The UV-vis spectrum of its polymer film also shows a very small temperature dependence. A cyclic voltammogram illustrates that the polymer can be reversibly n-doped and dedoped in a negative sweep and irreversibly p-doped during a positive sweep. All of the results demonstrate that the obtained polymer is a promising green-light emission material for PLED applications.
Source Title: Bulletin of the Chemical Society of Japan
URI: http://scholarbank.nus.edu.sg/handle/10635/66852
ISSN: 00092673
DOI: 10.1246/bcsj.72.1941
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