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|Title:||Fourier transform Raman spectral measurements of powdered quaternary mixtures of organic compounds. Exceptional pure component spectral reconstruction using band-target entropy minimization (BTEM)|
Band-target entropy minimization (BTEM)
|Citation:||Srilakshmi, C., Widjaja, E., Anderson, B.G., Garland, M. (2007-04-30). Fourier transform Raman spectral measurements of powdered quaternary mixtures of organic compounds. Exceptional pure component spectral reconstruction using band-target entropy minimization (BTEM). Talanta 72 (2) : 847-853. ScholarBank@NUS Repository. https://doi.org/10.1016/j.talanta.2006.11.037|
|Abstract:||Fourier transform Raman spectra of eight mixtures of four organic solids, namely dicyandiamide, melamine, acetamide and urea were measured. Matrices formed from these spectra were first subjected to singular value decomposition to obtain the right singular vectors. The right singular vectors were then subjected to blind source separation using band-target entropy minimization (BTEM), thus no a priori information (i.e. involving the nature of the components present, their spectra, nor their concentrations) was included in the analysis. The recovered pure component spectra are of exceptionally high quality and are consistent with pure reference spectra. Various empirical and statistical tests, such as the Euclidean norm and target transform factor analysis, were employed to assess the quality of the recovered spectra. The present results indicate the applicability of combined Raman and BTEM analysis for solid mixtures. © 2006 Elsevier B.V. All rights reserved.|
|Appears in Collections:||Staff Publications|
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