Please use this identifier to cite or link to this item: https://doi.org/10.1021/ma050536a
Title: Dual-brush-type amphiphilic triblock copolymer with intact epoxide functional groups from consecutive RAFT polymerizations and ATRP
Authors: Cheng, Z. 
Zhu, X.
Fu, G.D.
Kang, E.T. 
Neoh, K.G. 
Issue Date: 9-Aug-2005
Source: Cheng, Z., Zhu, X., Fu, G.D., Kang, E.T., Neoh, K.G. (2005-08-09). Dual-brush-type amphiphilic triblock copolymer with intact epoxide functional groups from consecutive RAFT polymerizations and ATRP. Macromolecules 38 (16) : 7187-7192. ScholarBank@NUS Repository. https://doi.org/10.1021/ma050536a
Abstract: The synthesis of dual-brush-type amphiphilic triblock copolymer with intact epoxide functional groups from consecutive reversible addition-fragmentation chain transfer (RAFT) and atom transfer radical polymerization (ATRP) polymerization, was described. Depending on its architecture and chemical composition, linear amphiphilic block copolymer can self-assemble into micelles, vesicles, and a variety of other morphologies. Results suggest that the molecular weights and composition of heterogeneous brush-type copolymers could be successfully controlled by the monomer to initiator feed ratios in combined RAFT and ATRP. It was found that the aggregates of nanosized spherical micelles are discernible.
Source Title: Macromolecules
URI: http://scholarbank.nus.edu.sg/handle/10635/63754
ISSN: 00249297
DOI: 10.1021/ma050536a
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