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|Title:||Dual-brush-type amphiphilic triblock copolymer with intact epoxide functional groups from consecutive RAFT polymerizations and ATRP|
|Authors:||Cheng, Z. |
|Source:||Cheng, Z., Zhu, X., Fu, G.D., Kang, E.T., Neoh, K.G. (2005-08-09). Dual-brush-type amphiphilic triblock copolymer with intact epoxide functional groups from consecutive RAFT polymerizations and ATRP. Macromolecules 38 (16) : 7187-7192. ScholarBank@NUS Repository. https://doi.org/10.1021/ma050536a|
|Abstract:||The synthesis of dual-brush-type amphiphilic triblock copolymer with intact epoxide functional groups from consecutive reversible addition-fragmentation chain transfer (RAFT) and atom transfer radical polymerization (ATRP) polymerization, was described. Depending on its architecture and chemical composition, linear amphiphilic block copolymer can self-assemble into micelles, vesicles, and a variety of other morphologies. Results suggest that the molecular weights and composition of heterogeneous brush-type copolymers could be successfully controlled by the monomer to initiator feed ratios in combined RAFT and ATRP. It was found that the aggregates of nanosized spherical micelles are discernible.|
|Appears in Collections:||Staff Publications|
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