Squeeze-out of branched alkanes on graphite

Abstract

We study squalane and heptamethylnonane (HMN) confined between a conducting atomic force microscope tip and a graphite surface. Solvation layering occurs for both liquids but marked differences in the squeeze out mechanics are observed for ordered or disordered monolayers. The squalane monolayer at 25°C is an ordered solid, as verified by direct imaging, and the squeeze out can be modeled using elastic continuum mechanics. HMN is in a disordered state at 25°C and cannot be modeled as a single elastic asperity even in solid-solid contact because HMN liquid is trapped in the contact zone. © 2008 The American Physical Society.