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|Title:||Stacking of double bonds for photochemical [2+2] cycloaddition reactions in the solid state|
|Authors:||Nagarathinam, M. |
|Citation:||Nagarathinam, M., Peedikakkal, A.M.P., Vittal, J.J. (2008). Stacking of double bonds for photochemical [2+2] cycloaddition reactions in the solid state. Chemical Communications (42) : 5277-5288. ScholarBank@NUS Repository. https://doi.org/10.1039/b809136f|
|Abstract:||trans-1,2-Bis(4-pyridyl)ethylene (bpe), containing a C=C bond, has been extensively studied for solid-state photochemical [2+2] cycloaddition reactions, in discrete molecular and metal complexes, hydrogen bonded and coordination polymeric structures. The challenges in orienting a pair or more of bpe molecules in the solid-state using crystal engineering principles, and their photochemical behaviour and implications, based on Schmidt's postulates, are discussed. © The Royal Society of Chemistry.|
|Source Title:||Chemical Communications|
|Appears in Collections:||Staff Publications|
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