Please use this identifier to cite or link to this item: https://doi.org/10.1039/b809136f
Title: Stacking of double bonds for photochemical [2+2] cycloaddition reactions in the solid state
Authors: Nagarathinam, M. 
Peedikakkal, A.M.P.
Vittal, J.J. 
Issue Date: 2008
Citation: Nagarathinam, M., Peedikakkal, A.M.P., Vittal, J.J. (2008). Stacking of double bonds for photochemical [2+2] cycloaddition reactions in the solid state. Chemical Communications (42) : 5277-5288. ScholarBank@NUS Repository. https://doi.org/10.1039/b809136f
Abstract: trans-1,2-Bis(4-pyridyl)ethylene (bpe), containing a C=C bond, has been extensively studied for solid-state photochemical [2+2] cycloaddition reactions, in discrete molecular and metal complexes, hydrogen bonded and coordination polymeric structures. The challenges in orienting a pair or more of bpe molecules in the solid-state using crystal engineering principles, and their photochemical behaviour and implications, based on Schmidt's postulates, are discussed. © The Royal Society of Chemistry.
Source Title: Chemical Communications
URI: http://scholarbank.nus.edu.sg/handle/10635/53355
ISSN: 13597345
DOI: 10.1039/b809136f
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