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|Title:||Miscibility as a function of copolymer composition in blends of a random copolymer and a homopolymer|
|Authors:||Hu, J. |
Differential scanning calorimetry
|Citation:||Hu, J., Abetz, V. (2004-05). Miscibility as a function of copolymer composition in blends of a random copolymer and a homopolymer. Colloid and Polymer Science 282 (7) : 716-721. ScholarBank@NUS Repository. https://doi.org/10.1007/s00396-003-1002-2|
|Abstract:||Random copolymers of n-butyl acrylate (BA) and cyclohexyl acrylate (CHA) were synthesized by solution polymerization in cyclohexane. Blends of polystyrene with the poly(CHA-stat-BA) copolymers were prepared by solvent casting and coprecipitation. The miscibility of the blends was characterized by means of differential scanning calorimetry. While blends with a low content of CHA in the copolymer showed two characteristic glass-transition temperatures of the corresponding blend components, those with a CHA content higher than 70% presented good compatibility. Phase separation of the miscible blends took place after annealing at 200°C for 1 h, which implies an upper miscibility gap (lower critical solution temperature. © Springer-Verlag 2004.|
|Source Title:||Colloid and Polymer Science|
|Appears in Collections:||Staff Publications|
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