Asymmetric organocatalytic cascade Michael/hemiketalization/retro-Henry reaction of β,γ-unsaturated ketoesters with α-nitroketones

Please use this identifier to cite or link to this item: https://doi.org/10.1039/c1cc11124h

Title:	Asymmetric organocatalytic cascade Michael/hemiketalization/retro-Henry reaction of β,γ-unsaturated ketoesters with α-nitroketones
Authors:	Gao, Y. Ren, Q. Siau, W.-Y. Wang, J.
Issue Date:	28-May-2011
Citation:	Gao, Y., Ren, Q., Siau, W.-Y., Wang, J. (2011-05-28). Asymmetric organocatalytic cascade Michael/hemiketalization/retro-Henry reaction of β,γ-unsaturated ketoesters with α-nitroketones. Chemical Communications 47 (20) : 5819-5821. ScholarBank@NUS Repository. https://doi.org/10.1039/c1cc11124h
Abstract:	An unprecedented enantioselective organocatalytic Michael/hemiketalization/ retro-Henry cascade sequence is described, which catalyzed by a simple bifunctional indane amine-thiourea catalyst. This process provides a new route to the enantioselective synthesis of 5-nitro-pent-2-enoates, a precursor to α-ketolactam. © 2011 The Royal Society of Chemistry.
Source Title:	Chemical Communications
URI:	http://scholarbank.nus.edu.sg/handle/10635/52803
ISSN:	13597345
DOI:	10.1039/c1cc11124h
Appears in Collections:	Staff Publications

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