Please use this identifier to cite or link to this item: https://doi.org/10.1039/c1cc11124h
Title: Asymmetric organocatalytic cascade Michael/hemiketalization/retro-Henry reaction of β,γ-unsaturated ketoesters with α-nitroketones
Authors: Gao, Y.
Ren, Q.
Siau, W.-Y.
Wang, J. 
Issue Date: 28-May-2011
Source: Gao, Y., Ren, Q., Siau, W.-Y., Wang, J. (2011-05-28). Asymmetric organocatalytic cascade Michael/hemiketalization/retro-Henry reaction of β,γ-unsaturated ketoesters with α-nitroketones. Chemical Communications 47 (20) : 5819-5821. ScholarBank@NUS Repository. https://doi.org/10.1039/c1cc11124h
Abstract: An unprecedented enantioselective organocatalytic Michael/hemiketalization/ retro-Henry cascade sequence is described, which catalyzed by a simple bifunctional indane amine-thiourea catalyst. This process provides a new route to the enantioselective synthesis of 5-nitro-pent-2-enoates, a precursor to α-ketolactam. © 2011 The Royal Society of Chemistry.
Source Title: Chemical Communications
URI: http://scholarbank.nus.edu.sg/handle/10635/52803
ISSN: 13597345
DOI: 10.1039/c1cc11124h
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