Please use this identifier to cite or link to this item:
|Title:||Molten salt synthesis and energy storage studies on CuCo 2O 4 and CuO·Co 3O 4|
|Authors:||Reddy, M.V. |
|Source:||Reddy, M.V., Yu, C., Jiahuan, F., Loh, K.P., Chowdari, B.V.R. (2012-10-21). Molten salt synthesis and energy storage studies on CuCo 2O 4 and CuO·Co 3O 4. RSC Advances 2 (25) : 9619-9625. ScholarBank@NUS Repository. https://doi.org/10.1039/c2ra21033a|
|Abstract:||CuCo 2O 4 and CuO·Co 3O 4 compounds were prepared by a one-pot simple molten salt method (MSM) at 280 °C to 750 °C. Changes in morphology, crystal structure and electrochemical properties of CuCo 2O 4 as a function of preparation temperatures were investigated using X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and Brunauer-Emmett-Teller absorption isotherm. XRD patterns of the sample prepared at 280 °C show a crystalline cubic structure with a lattice parameter value of a = 8.131 Å and a surface area value of 9.8 m 2 g -1. The sample prepared at temperatures >510 °C shows the presence of CuO·Co 3O 4 phases. Energy storage properties are evaluated using cyclic voltammetry (CV) and galvanostatic cycling studies. CV studies show a main anodic peak at ∼2.1 V and cathodic peak at ∼1.2 V. At a current rate of 60 mA g -1 and in the voltage range of 0.005-3.0 V vs. Li, CuCo 2O 4 composite prepared at 510 °C shows a high and stable capacity of ∼680 (quenched) and 740 (slow cooling) mAh g -1 at the end of the 40th cycle. © The Royal Society of Chemistry. 2012.|
|Source Title:||RSC Advances|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Jan 17, 2018
WEB OF SCIENCETM
checked on Nov 14, 2017
checked on Jan 14, 2018
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.