Please use this identifier to cite or link to this item: http://scholarbank.nus.edu.sg/handle/10635/113211
Title: Synthesis and structure of [{Cl 2Cd(dabco-CH 2Cl)} 2(μ-Cl) 2]
Authors: Sampanthar, J.T. 
Vittal, J.J. 
Issue Date: 2001
Citation: Sampanthar, J.T.,Vittal, J.J. (2001). Synthesis and structure of [{Cl 2Cd(dabco-CH 2Cl)} 2(μ-Cl) 2]. Main Group Metal Chemistry 24 (2) : 127-128. ScholarBank@NUS Repository.
Abstract: Reaction of CdCl 2 with 1,4-diazabicyclo[2,2,2]octane (dabco) in CH 2Cl 2 solvent gave a neutral binuclear chloride bridged cadmium (II) complex, [{Cl 2Cd(dabco-CH 2Cl)} 2(μ-Cl) 2], 1 which was characterized by 1H and 13C NMR spectroscopy in solution and by X-ray crystallography in the solid state. In 1, the Cd(II) centers are bonded to two terminal and two doubly bridging chloride atoms and a nitrogen atom of the alkylated dabco ligand to have trigonal bipyramidal geometry.
Source Title: Main Group Metal Chemistry
URI: http://scholarbank.nus.edu.sg/handle/10635/113211
ISSN: 07921241
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

Page view(s)

42
checked on Sep 21, 2018

Google ScholarTM

Check


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.