Synthesis and structure of [{Cl 2Cd(dabco-CH 2Cl)} 2(μ-Cl) 2]

Please use this identifier to cite or link to this item: https://scholarbank.nus.edu.sg/handle/10635/113211

Title:	Synthesis and structure of [{Cl 2Cd(dabco-CH 2Cl)} 2(μ-Cl) 2]
Authors:	Sampanthar, J.T. Vittal, J.J.
Issue Date:	2001
Citation:	Sampanthar, J.T.,Vittal, J.J. (2001). Synthesis and structure of [{Cl 2Cd(dabco-CH 2Cl)} 2(μ-Cl) 2]. Main Group Metal Chemistry 24 (2) : 127-128. ScholarBank@NUS Repository.
Abstract:	Reaction of CdCl 2 with 1,4-diazabicyclo[2,2,2]octane (dabco) in CH 2Cl 2 solvent gave a neutral binuclear chloride bridged cadmium (II) complex, [{Cl 2Cd(dabco-CH 2Cl)} 2(μ-Cl) 2], 1 which was characterized by 1H and 13C NMR spectroscopy in solution and by X-ray crystallography in the solid state. In 1, the Cd(II) centers are bonded to two terminal and two doubly bridging chloride atoms and a nitrogen atom of the alkylated dabco ligand to have trigonal bipyramidal geometry.
Source Title:	Main Group Metal Chemistry
URI:	http://scholarbank.nus.edu.sg/handle/10635/113211
ISSN:	07921241
Appears in Collections:	Staff Publications

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