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|Title:||Assembly of the TAN-1057 A/B heterocycle from a dehydroalanine precursor|
|Citation:||Lin, P.,Ganesan, A. (2000). Assembly of the TAN-1057 A/B heterocycle from a dehydroalanine precursor. Synthesis (14) : 2127-2130. ScholarBank@NUS Repository.|
|Abstract:||A tandem reaction process was used to form the tetrahydropyrimidinone core of the TAN-1057 A and B dipeptide antibiotics. Michael addition of ammonia to a dehydroalanine derivative, followed by intramolecular displacement of an S-methylisothiourea assembles the tetrahydropyrimidinone in one-step.|
|Appears in Collections:||Staff Publications|
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