Please use this identifier to cite or link to this item: https://doi.org/10.1016/S0022-0248(01)00811-9
Title: The development of RAS and RHEED as in situ probes to monitor dopant segregation in GS-MBE on Si (0 0 1)
Authors: Hartell, A.D.
Tok, E.S. 
Zhang, J.
Keywords: A1. Doping
A1. Segregation
A3. Chemical vapour deposition processes
A3. Molecular beam epitaxy
B2. Semiconducting silicon
B2. Semiconducting silicon compounds
Issue Date: Jul-2001
Citation: Hartell, A.D., Tok, E.S., Zhang, J. (2001-07). The development of RAS and RHEED as in situ probes to monitor dopant segregation in GS-MBE on Si (0 0 1). Journal of Crystal Growth 227-228 : 729-734. ScholarBank@NUS Repository. https://doi.org/10.1016/S0022-0248(01)00811-9
Abstract: Assessment of surface arsenic coverage during epitaxial growth of n-type doped Si is essential to the understanding of dopant incorporation and segregation behaviour. This particular problem is investigated using reflectance anisotropy spectroscopy (RAS) and reflection high energy electronic diffraction (RHEED) intensity oscillation technique as in situ probes. Initial measurement and analysis show that RAS is extremely sensitive to the presence of As on vicinal Si(0 0 1) surfaces and that the changes in the RA response at 2.6 eV are approximately linear to the As surface coverage produced by repeated cycles of low temperature adsorption of arsine followed by thermal desorption of hydrogen. For singular Si(0 0 1) surfaces where RAS cannot be applied, RHEED intensity oscillations were used to follow the change in As surface concentration during the growth of an Si capping layer over pre-deposited As. Using a model of the influence of As on the Si growth rate from Si hydrides, a surface As concentration profile was obtained and compared with that predicted by a model of As surface segregation. The results were in good agreement with secondary ion mass spectrometry measurements of a similar sample. © 2001 Elsevier Science B.V.
Source Title: Journal of Crystal Growth
URI: http://scholarbank.nus.edu.sg/handle/10635/107316
ISSN: 00220248
DOI: 10.1016/S0022-0248(01)00811-9
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