Homogeneous nucleation catastrophe as a kinetic stability limit for superheated crystal

Abstract

Homogeneous nucleation kinetics for melting in superheated crystals is analyzed in order to derive a kinetic stability limit for the crystal lattice above its equilibrium melting point (Tm). It is found that at a critical temperature (Tm K, which is about 1.2Tm for various elemental metals) a massive homogeneous nucleation of melting occurs in the superheated crystal. Such a homogeneous nucleation catastrophe, which occurs before other proposed (rigidity, volume, and entropy) catastrophes can intervene, provides us with a kinetic stability limit for superheated crystals.