Zhang, T.H.Liu, X.Y.PHYSICS2014-10-162014-10-162009-02-02Zhang, T.H., Liu, X.Y. (2009-02-02). Nucleation: What happens at the initial stage?. Angewandte Chemie - International Edition 48 (7) : 1308-1312. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.20080474314337851https://scholarbank.nus.edu.sg/handle/10635/97391Crystallizing growth: The initial structure of crystal unclei is supersaturation-dependent. At low degrees of supersaturation, liquid-like nuclei are formed initially, which undergo a continuous structure transition from liquid-like to crystal-like as the size N increases. This gradual structure evolution substantially lowers the nucleation barrier ΔGz.ast; and facilitates the nucleation relative to the formation of crystal-like clusters from the beggining. © 2009 Wiley-VCH Verleg GmbH & Co. KGaA.ColloidsCrystal engineeringCrystal growthNucleationArticle000263492400022