Please use this identifier to cite or link to this item: https://scholarbank.nus.edu.sg/handle/10635/98652
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dc.titleChemical reaction of amides and hydrides
dc.contributor.authorXiong, Z.
dc.contributor.authorHu, J.
dc.contributor.authorWu, G.
dc.contributor.authorChen, P.
dc.date.accessioned2014-10-16T09:49:47Z
dc.date.available2014-10-16T09:49:47Z
dc.date.issued2005
dc.identifier.citationXiong, Z.,Hu, J.,Wu, G.,Chen, P. (2005). Chemical reaction of amides and hydrides. ACS Division of Fuel Chemistry, Preprints 50 (2) : 501-502. ScholarBank@NUS Repository.
dc.identifier.issn05693772
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/98652
dc.description.abstractFive novel Metal-N-H systems were developed accordingly, among which three systems could release substantial amount of hydrogen (> 4.2 wt %) near ambient temperature. As the H-deficient phase of Metal-N-H was somewhat with imide-like behavior, the following equation may account for the general features of the amide-hydride reaction: M1-NH2 + M2Hn → (M1-M2-NH) + H2. M1 and M2 represented alkali and/or alkali earth metals. Structural changes before and after interaction were rather important. However, the poor crystallinity of the ball milled samples brings difficulties for the X-ray characterization. The challenges posed to the Metal-N-H system for hydrogen storage purpose were the reversibility (especially for those ambient temperature systems), capacity, and the chemical stability. This is an abstract of a paper presented at the ACS Fuel Chemistry Meeting (Washington, DC Fall 2005).
dc.sourceScopus
dc.typeConference Paper
dc.contributor.departmentPHYSICS
dc.description.sourcetitleACS Division of Fuel Chemistry, Preprints
dc.description.volume50
dc.description.issue2
dc.description.page501-502
dc.identifier.isiutNOT_IN_WOS
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