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https://doi.org/10.1016/S1386-1425(99)00056-6
| Title: | v3 band of DCOOH | Authors: | Goh, K.L. Ong, P.P. Tan, T.L. |
Issue Date: | Nov-1999 | Citation: | Goh, K.L., Ong, P.P., Tan, T.L. (1999-11). v3 band of DCOOH. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy 55 (13) : 2601-2614. ScholarBank@NUS Repository. https://doi.org/10.1016/S1386-1425(99)00056-6 | Abstract: | The high resolution Fourier transform infrared (FTIR) spectrum of the v3 band of DCOOH has been measured with a resolution of 0.004 cm-1 in the spectral range 1670-1810 cm-1. Using the Watson's A-reduced Hamiltonian in the Ir representation, 713 infrared transitions have been assigned and fitted to provide rovibrational constants for the v3 = 1 state with a standard deviation of 0.000439 cm-1. The v3 band centre was found at 1725.87497±0.00003 cm-1. The band is perturbed by the 2v8 band, situated at 1762.9 cm-1, through Fermi resonance and possibly a Coriolis term. Perturbations of v3 by v5+v7 and v5+v9 are also expected. About 280 perturbed v3 lines were identified and excluded in the final fit. | Source Title: | Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy | URI: | http://scholarbank.nus.edu.sg/handle/10635/98541 | ISSN: | 13861425 | DOI: | 10.1016/S1386-1425(99)00056-6 |
| Appears in Collections: | Staff Publications |
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