Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jphotochem.2010.04.008
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dc.titleSynthesis, third-order nonlinear absorption and refraction of fullerene dyads containing fluorene
dc.contributor.authorOuyang, X.
dc.contributor.authorZeng, G.
dc.contributor.authorZeng, H.
dc.contributor.authorJi, W.
dc.date.accessioned2014-10-16T09:44:18Z
dc.date.available2014-10-16T09:44:18Z
dc.date.issued2010-06-10
dc.identifier.citationOuyang, X., Zeng, G., Zeng, H., Ji, W. (2010-06-10). Synthesis, third-order nonlinear absorption and refraction of fullerene dyads containing fluorene. Journal of Photochemistry and Photobiology A: Chemistry 213 (1) : 7-13. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jphotochem.2010.04.008
dc.identifier.issn10106030
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/98210
dc.description.abstractTwo new fullerene-fluorene dyads, N-methyl-2-(2-fluorenyl)-3,4-[60]fuller-pyrrolydine (1) and N-methyl-2-(2-fluorenyl)-3,4-[70]fullerpyrrolydine (2), were synthesized and their structures were confirmed by MALDI-MS, 1H NMR and FT-IR. Their electrochemical and optical properties were investigated by cyclic voltammetry and Z-scan technique, including, electronic potentials, two-photon absorption cross-sections (σ2), nonlinear refractive indexes (n2), microscopic second-order hyperpolarizabilities (γR) and third-order nonlinear susceptibilities (χI (3) and χR (3)). Importantly, the χI (3) and σ2 in 2 were increased above 35% due to [70]fullerene unit than that of 1. © 2010 Elsevier B.V. All rights reserved.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.jphotochem.2010.04.008
dc.sourceScopus
dc.subjectFullerene-fluorene
dc.subjectNonlinear optical properties
dc.subjectTwo-photon absorption
dc.typeArticle
dc.contributor.departmentPHYSICS
dc.description.doi10.1016/j.jphotochem.2010.04.008
dc.description.sourcetitleJournal of Photochemistry and Photobiology A: Chemistry
dc.description.volume213
dc.description.issue1
dc.description.page7-13
dc.description.codenJPPCE
dc.identifier.isiut000279969400002
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