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|Title:||Synthesis, third-order nonlinear absorption and refraction of fullerene dyads containing fluorene||Authors:||Ouyang, X.
Nonlinear optical properties
|Issue Date:||10-Jun-2010||Citation:||Ouyang, X., Zeng, G., Zeng, H., Ji, W. (2010-06-10). Synthesis, third-order nonlinear absorption and refraction of fullerene dyads containing fluorene. Journal of Photochemistry and Photobiology A: Chemistry 213 (1) : 7-13. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jphotochem.2010.04.008||Abstract:||Two new fullerene-fluorene dyads, N-methyl-2-(2-fluorenyl)-3,4-fuller-pyrrolydine (1) and N-methyl-2-(2-fluorenyl)-3,4-fullerpyrrolydine (2), were synthesized and their structures were confirmed by MALDI-MS, 1H NMR and FT-IR. Their electrochemical and optical properties were investigated by cyclic voltammetry and Z-scan technique, including, electronic potentials, two-photon absorption cross-sections (σ2), nonlinear refractive indexes (n2), microscopic second-order hyperpolarizabilities (γR) and third-order nonlinear susceptibilities (χI (3) and χR (3)). Importantly, the χI (3) and σ2 in 2 were increased above 35% due to fullerene unit than that of 1. © 2010 Elsevier B.V. All rights reserved.||Source Title:||Journal of Photochemistry and Photobiology A: Chemistry||URI:||http://scholarbank.nus.edu.sg/handle/10635/98210||ISSN:||10106030||DOI:||10.1016/j.jphotochem.2010.04.008|
|Appears in Collections:||Staff Publications|
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