Synthesis, third-order nonlinear absorption and refraction of fullerene dyads containing fluorene

Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jphotochem.2010.04.008

Title:	Synthesis, third-order nonlinear absorption and refraction of fullerene dyads containing fluorene
Authors:	Ouyang, X. Zeng, G. Zeng, H. Ji, W.
Keywords:	Fullerene-fluorene Nonlinear optical properties Two-photon absorption
Issue Date:	10-Jun-2010
Citation:	Ouyang, X., Zeng, G., Zeng, H., Ji, W. (2010-06-10). Synthesis, third-order nonlinear absorption and refraction of fullerene dyads containing fluorene. Journal of Photochemistry and Photobiology A: Chemistry 213 (1) : 7-13. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jphotochem.2010.04.008
Abstract:	Two new fullerene-fluorene dyads, N-methyl-2-(2-fluorenyl)-3,4-[60]fuller-pyrrolydine (1) and N-methyl-2-(2-fluorenyl)-3,4-[70]fullerpyrrolydine (2), were synthesized and their structures were confirmed by MALDI-MS, 1H NMR and FT-IR. Their electrochemical and optical properties were investigated by cyclic voltammetry and Z-scan technique, including, electronic potentials, two-photon absorption cross-sections (σ2), nonlinear refractive indexes (n2), microscopic second-order hyperpolarizabilities (γR) and third-order nonlinear susceptibilities (χI (3) and χR (3)). Importantly, the χI (3) and σ2 in 2 were increased above 35% due to [70]fullerene unit than that of 1. © 2010 Elsevier B.V. All rights reserved.
Source Title:	Journal of Photochemistry and Photobiology A: Chemistry
URI:	http://scholarbank.nus.edu.sg/handle/10635/98210
ISSN:	10106030
DOI:	10.1016/j.jphotochem.2010.04.008
Appears in Collections:	Staff Publications

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