Please use this identifier to cite or link to this item:
https://doi.org/10.1016/S0277-5387(00)00399-5
DC Field | Value | |
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dc.title | Synthesis, crystal structure and third-order optical nonlinearity of a 'flywheel'-shaped cluster, [MoS4Cu3(dppm)3][BF4]·2H2O | |
dc.contributor.author | Tan, W. | |
dc.contributor.author | Zheng, H. | |
dc.contributor.author | Jin, Q. | |
dc.contributor.author | Jin, G. | |
dc.contributor.author | Ji, W. | |
dc.contributor.author | Long, D. | |
dc.contributor.author | Xin, X. | |
dc.date.accessioned | 2014-10-16T09:44:12Z | |
dc.date.available | 2014-10-16T09:44:12Z | |
dc.date.issued | 2000-07-01 | |
dc.identifier.citation | Tan, W., Zheng, H., Jin, Q., Jin, G., Ji, W., Long, D., Xin, X. (2000-07-01). Synthesis, crystal structure and third-order optical nonlinearity of a 'flywheel'-shaped cluster, [MoS4Cu3(dppm)3][BF4]·2H2O. Polyhedron 19 (13) : 1545-1549. ScholarBank@NUS Repository. https://doi.org/10.1016/S0277-5387(00)00399-5 | |
dc.identifier.issn | 02775387 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/98202 | |
dc.description.abstract | The title compound [MoS4Cu3(dppm)3][BF4]]·2H2O (dppm = Ph2PCH2PPh2) was synthesized for nonlinear optical studies by the reaction of (Et4N)2MoS4 and [Cu2(dppm)2(MeCN)4][BF4]2 in CH3CN solution. Single-crystal X-ray analysis revealed that three copper atoms and the MoS4/2- form a distorted 'flywheel' array with W-Cu separations of 2.7754(14), 2.792(2) and 2.820 (2) Å. The third-order nonlinear optical properties were investigated by a Z-scan technique with 7 ns laser pulses at 532 nm. It was observed that the nonlinear absorption is very small, but it has considerable third-order large nonlinear refractive index. (C) 2000 Elsevier Science Ltd. | |
dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/S0277-5387(00)00399-5 | |
dc.source | Scopus | |
dc.subject | Copper compounds | |
dc.subject | Crystal structures | |
dc.subject | Dppm | |
dc.subject | Nonlinear optical properties | |
dc.subject | Synthesis | |
dc.subject | Tetrathiometalate | |
dc.type | Article | |
dc.contributor.department | PHYSICS | |
dc.description.doi | 10.1016/S0277-5387(00)00399-5 | |
dc.description.sourcetitle | Polyhedron | |
dc.description.volume | 19 | |
dc.description.issue | 13 | |
dc.description.page | 1545-1549 | |
dc.description.coden | PLYHD | |
dc.identifier.isiut | 000088923700002 | |
Appears in Collections: | Staff Publications |
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