Please use this identifier to cite or link to this item: https://doi.org/10.1016/S0020-1693(00)00104-3
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dc.titleSyntheses, crystal structures and nonlinear optical properties of MS4Pd(dppp) (M = Mo, W)
dc.contributor.authorZheng, H.-G.
dc.contributor.authorTan, W.-L.
dc.contributor.authorJin, G.-C.
dc.contributor.authorJi, W.
dc.contributor.authorJin, Q.-H.
dc.contributor.authorHuang, X.-Y.
dc.contributor.authorXin, X.-Q.
dc.date.accessioned2014-10-16T09:43:49Z
dc.date.available2014-10-16T09:43:49Z
dc.date.issued2000-07-14
dc.identifier.citationZheng, H.-G., Tan, W.-L., Jin, G.-C., Ji, W., Jin, Q.-H., Huang, X.-Y., Xin, X.-Q. (2000-07-14). Syntheses, crystal structures and nonlinear optical properties of MS4Pd(dppp) (M = Mo, W). Inorganica Chimica Acta 305 (1) : 14-18. ScholarBank@NUS Repository. https://doi.org/10.1016/S0020-1693(00)00104-3
dc.identifier.issn00201693
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/98168
dc.description.abstractThe title compounds [MS4Pd(dppp)] [M = Mo (1), W (2); dppp = Ph2PCH2CH2CH2PPh2] were synthesized for nonlinear optical studies by the reaction of (Et4N)2MS4 (M = Mo, W) and (dppp)PdCl2 in the CH2Cl2-CH3CN. Single-crystal X-ray analyses revealed that the two compounds consisted of a distorted tetrahedral MS4 (M = Mo, W) unit with a Pd atom and two S atom bridges. The Pd atom has a cis-quasisquare coordination geometry with two P donors of dppp and two S donors of MS4. The nonlinear optical properties of 1 and 2 were investigated by a Z-scan technique with 7 ns laser pulses at 532 nm. It was observed that the nonlinear absorption for 1 is very small, but it has considerable large nonlinear refractive index; no nonlinear optical behavior was observed for 2, although it shows a similar structure to that of compound 1. (C) 2000 Elsevier Science S.A.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/S0020-1693(00)00104-3
dc.sourceScopus
dc.subjectCrystal structures
dc.subjectOptical properties
dc.subjectPalladium complexes
dc.subjectThiometallate complexes
dc.typeArticle
dc.contributor.departmentPHYSICS
dc.description.doi10.1016/S0020-1693(00)00104-3
dc.description.sourcetitleInorganica Chimica Acta
dc.description.volume305
dc.description.issue1
dc.description.page14-18
dc.description.codenICHAA
dc.identifier.isiut000088056600003
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